Alternatives to Using Tetrochloroethylene
People with a long memory of drycleaning may remember when professional
cleaning was done in centralized locations using benzene, carbon tetrachloride,
or petroleum solvents, as well as water, and the neighborhood cleaning
shop was a drop off point often with tailoring the main on-site occupation.
Turn-around time was generally a week or more.
After the Second World War, consumers demanded faster turnaround. To
meet this, the industry decentralized. The introduction of perc helped:
here was a solvent which was non-flammable and safe to handle, and which
used equipment economical enough to be installed in the neighborhood drycleaning
shop. Same-day service became a reality.
Since that time, perc drycleaning has been able to carry drycleaners
through a variety
of changes in fashion -- even including the polyester leisure suit.
The 1990s have brought a new health and environmental challenge. New methods
of tracing extremely small quantities of chemicals in the environment --
in urban air, groundwater, soil and the atmosphere of both the workplace
and the home -- have led to stringent laws governing waste emissions and
waste disposal. And they have led to consumer advocacy groups who call
for no trace chemicals in the environment.
Advantages of perc;
Perchloroethylene has been the principal drycleaning
solvent for a number of years becaues;
-
Its high solvency (KB value of 90) dissolves most of the oils, grease and
fats the drycleaner is faced with. Detergents and spotting chemicals have
been developed for the other stains and soils.
-
Perc's low viscosity (0.84 centipoise) and low surface tension (32
dynes/cm) allow it to penetrate fibers rapidly to dissolve soils.Because
perc is hydrophobic, it doesn't swell the fibers.
-
The high density of perc (13.5 lbs./gal.) not only facilitates mechanical
action in the washing cycle, it also helps the separation of solvent from
water in the recovery process.
-
Its high evaporation rate (1.5 compared to n-butyl alcohol, the standard)
provides for reasonable drying times at moderate temperatures. Most importantly,
it was perc's virtual non-flammability that led to its wide use when decentralized
drycleaning plants became standard in the industry after World War II.
Addressing the hazards Comparing perc, then, to our list of considerations,
we find that it fills the needs of drycleaners in almost all respects.
The key concerns are, as with any chemical, understanding the hazards.
In this case understanding the toxicity issues and whether it is or is
not a human carcinogen. To address these hazards, a perc-based process
has to control emissions so that employees and the public get as little
exposure as possible, thus minimizing the potential risk.
As far as toxicity is concerned, there is virtually no risk to employees
or customers of a drycleaning plant when the solvent is handled properly.
Most current regulations are based primarily on toxicology studies, including
cancer studies, which were done on laboratory animals. However, different
species of animals, including humans, metabolize chemicals differently.
Thus, one cannot assume that a cancer effect in one animal species will
predict cancer in another species without
understanding the metabolic processes in the species.
Perc producers, trade associations, industry experts and many independent
scientists agree that when you consider all the available scientific evidence,
there is no cancer risk to humans when perc is used properly. In fact,
the science advisory board of the U.S. Environmental Protection Agency
(EPA) has concluded that "there is no compelling evidence of human cancer
risk" for perc.
The practice of including an assessment of the metabolic differences
of species is now acknowledged by regulators, and it is just now being
included in the process regulators follow for risk assessments.
Producers of perchloroethylene, committed to the continued safe use
of this solvent, support the industry in two ways. They are funding additional
long term health studies which will ultimately help answer these complicated
questions. They are also working with regulatory agencies to make sure
that the most advanced scientific methods are used to evaluate perc.
Janet Hickman is Dow's drycleaning industry development leader
and perchloroethylene product steward. This article is based on a presentation
she gave in Arizona last year. It was originally published in the summer
1997 issue of Dow's Spot News.
Alternative #1 - Green Clean
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A pleasantly scented, all-purpose cleaner designed
for the rapid removal of grease
and other heavy soils. It can be used right out of the bottle or diluted
for milder jobs. It instantly penetrates greasy and oily surfaces, providing
powerful emulsifying ingredients that chemically soften and dissolve the
deposits, making them easy to remove. The safer, effective, alternative
to toxic cleaners, bleaches and solvents. It's non-corrosive and very economical
to use (Calgon
Products, 1997).
-
Grants Notes; Green
Clean is a considerable amout of addition work in that employees must manually
apply the cleaner. However, including the additional labour, Green Clean
is more economical.
-
View
MSDS
Alternative #2 - Dyrel
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Dryel uses biodegradable cleaning agents.
Additionally, the dryer bag is

reusable and the refill packaging is made from 100%- recycled
paperboard. The plastic lid is also made from 100%- recycled
plastic
(PET). The Dryel Bag is designed for multiple uses (up to
20 cycles). To reduce
waste, we've designed a consumer-friendly refill which uses
49% less
packaging than the primary kit and is made from 100% recycled
fiber.
We've also found that many consumers have used the bag for
trash
(Proctor
and Gamble, Dryel, 1998).
-
Grants Notes; It is important to note that
this is an 'at home' Drycleaning product. This product has not yet been
on shelves for a full year, and is still in it's 'personal use' trial stage.
MSDS sheets are not available at the Proctor and Gamble web-sight. Although
this product is quite new, it appears to have excellent potential. Proctor
and Gamble has conducted extensive research and placed a great deal of
effort into maximizing the biodegradability of the product.
Alternative #3 - Liquid Carbon Dioxide
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Below 88 degrees Fahrenheit, at less than a thousand pounds of pressure,
carbon
dioxide
gas (CO-2) becomes a liquid.Over a 25- to 30-minute period under laboratory-controlled
conditions, the reusable clear liquid lifts stains from fabric. "It's environmentally
friendly," says Los Alamos researcher Craig Taylor, "because CO-2 doesn't
react with anything." different fabrics, including whites and colored
garments, can be cleaned at the same time because the CO-2 do not
act as a color-removing bleach (CNN,Pressing
Issue, 1996).
-
Grants Notes; Although,
this product promises near miracles, and is said to be environmentaly friendly,
this is highly questionable. Logic would dictate that the usind carbon
dioxide in its liquid state may present environmental problems. More information
regarding disposal, treatment and safety precaution is required to make
a clear judgement.
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